LewisBasicityandAffinityScales:DataandMeasurement
- 作者
- 出版社 Wiley
- 出版时间 2010年2月
- ISBN 9780470749579
- 定价 1459.40
内容简介
TheLewisconceptofacidsandbasesisdiscussedineverygeneral,organicandinorganicchemistrytextbook.Thisisusuallyjustadescriptivetreatment,asitisnotpossibletodeviseasinglenumericalscalesuitableforalloccasions.HoweverquantitativeLewisacid-basechemistrycanbedevelopedbycompilingreaction-specificbasicityscaleswhichcanbeusedinspecificbranchesofchemistryandbiochemistry.LewisBasicityandAffinityScales:DataandMeasurementbringstogetherforthefirsttimeacomprehensiverangeofLewisbasicity/affinitydatainonevolume.Morethan2400equilibriumconstantsofacid-basereactions,1500complexationenthalpies,andnearly2000infraredandultravioletshiftsuponcomplexationaregatheredtogetherin25thermodynamicandspectroscopicscalesofbasicityand/oraffinity.Foreachscale,thedefinition,themethodofmeasurement,anexhaustivedatabase,andacriticaldiscussionaregiven.Allthedatahavebeencriticallyexamined;somehavebeenre-measured;literaturegapshavebeenfilledbyoriginalmeasurements;andeachscalehasbeenmadehomogeneous.Topicscoveredinclude:Lewisbasicityandaffinitymeasurements:definitionsandcontext.theDonorNumberorSbCl5affinityscale.theBF3affinityscale.thermodynamicandspectroscopicscalesofhydrogen-bondbasicity.thermodynamicandspectroscopicscalesofhalogen-bondbasicity.gas-phasecationbasicityandaffinityscales.themeasurementofLewisbasicityandaffinityinthelaboratoryThiscollectionofdatawillenableexperimentalchemiststobetterunderstandandpredictthenumerouschemical,physicalandbiologicalpropertiesthatdependuponLewisbasicity.Chemometricianswillbeabletoapplytheirmethodstothedatamatricesconstructedfromthisbookinordertoidentifythefactorswhichinfluencebasicityandbasicity-dependentproperties.Inaddition,measuredexperimentalbasicitiesandaffinitiesareessentialtocomputationalchemistsforthevalidation,calibrationandestablishmentofreliablecomputationalmethodsforquantifyingandexplainingintermolecularforcesandthechemicalbond.LewisBasicityandAffinityScales:DataandMeasurementisanessentialsingle-sourcedesktopreferenceforresearchscientists,engineers,andstudentsinacademia,researchinstitutesandindustry,inallareasofchemistryfromfundamentaltoappliedresearch.
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